"A cyclohexane conformation is any of several three-dimensional shapes that a cyclohexane molecule can assume while maintaining the integrity of its chemical bonds.
The internal angles of a flat regular hexagon are 120°, while the preferred angle between successive bonds in a carbon chain is about 109.5°, the tetrahedral angle. Therefore the cyclohexane ring tends to assume certain non-planar (warped) conformations, which have all angles closer to 109.5° and therefore a lower strain energy than the flat hexagonal shape. The most important shapes are called chair, half-chair, boat, and twist-boat. The molecule can easily switch between these conformations, and only two of them - chair and twist-boat - can be isolated in pure form.
Cyclohexane conformations have been extensively studied in organic chemistry because they are the classical example of conformational isomerism and have noticeable influence on the physical and chemical properties of cyclohexane." [Cyclohexane conformation. Wikipedia]
The chemical drawing example "Cycloalkanes conformations" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.
The internal angles of a flat regular hexagon are 120°, while the preferred angle between successive bonds in a carbon chain is about 109.5°, the tetrahedral angle. Therefore the cyclohexane ring tends to assume certain non-planar (warped) conformations, which have all angles closer to 109.5° and therefore a lower strain energy than the flat hexagonal shape. The most important shapes are called chair, half-chair, boat, and twist-boat. The molecule can easily switch between these conformations, and only two of them - chair and twist-boat - can be isolated in pure form.
Cyclohexane conformations have been extensively studied in organic chemistry because they are the classical example of conformational isomerism and have noticeable influence on the physical and chemical properties of cyclohexane." [Cyclohexane conformation. Wikipedia]
The chemical drawing example "Cycloalkanes conformations" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.
The vector stencils library "Conformations" contains 32 symbols of ring conformations, Newman and Fisher projections for chemical and biochemical drawing the molecular models and structural formulas of organic molecules and biochemical metabolites. It is useful in stereochemistry for drawing spatial structures of conformers of organic molecules, and schemes of stereospecific chemical reactions in organic synthesis.
"In chemistry, conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted exclusively by rotations about formally single bonds (refer to figure on single bond rotation). Such isomers are generally referred to as conformational isomers or conformers and, specifically, as rotamers. Rotations about single bonds are restricted by a rotational energy barrier which must be overcome to interconvert one conformer to another. Conformational isomerism arises when the rotation about a single bond is relatively unhindered. That is, the energy barrier must be small enough for the interconversion to occur.
Conformational isomers are thus distinct from the other classes of stereoisomers (i. e. configurational isomers) where interconversion necessarily involves breaking and reforming of chemical bonds. For example, L- & D and R- & S- configurations of organic molecules have different handedness and optical activities, and can only be interconverted by breaking one or more bonds connected to the chiral atom and reforming a similar bond in a different direction or spatial orientation.
The study of the energetics between different rotamers is referred to as conformational analysis. It is useful for understanding the stability of different isomers, for example, by taking into account the spatial orientation and through-space interactions of substituents. In addition, conformational analysis can be used to predict and explain product(s) selectivity, mechanisms, and rates of reactions." [Conformational isomerism. Wikipedia]
The chemical symbols example "Design elements - Conformations" was created using the ConceptDraw PRO software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.
"In chemistry, conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted exclusively by rotations about formally single bonds (refer to figure on single bond rotation). Such isomers are generally referred to as conformational isomers or conformers and, specifically, as rotamers. Rotations about single bonds are restricted by a rotational energy barrier which must be overcome to interconvert one conformer to another. Conformational isomerism arises when the rotation about a single bond is relatively unhindered. That is, the energy barrier must be small enough for the interconversion to occur.
Conformational isomers are thus distinct from the other classes of stereoisomers (i. e. configurational isomers) where interconversion necessarily involves breaking and reforming of chemical bonds. For example, L- & D and R- & S- configurations of organic molecules have different handedness and optical activities, and can only be interconverted by breaking one or more bonds connected to the chiral atom and reforming a similar bond in a different direction or spatial orientation.
The study of the energetics between different rotamers is referred to as conformational analysis. It is useful for understanding the stability of different isomers, for example, by taking into account the spatial orientation and through-space interactions of substituents. In addition, conformational analysis can be used to predict and explain product(s) selectivity, mechanisms, and rates of reactions." [Conformational isomerism. Wikipedia]
The chemical symbols example "Design elements - Conformations" was created using the ConceptDraw PRO software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.
- Draw The Isomers Of Cyclopropane And Their Conformation And
- Conformation Isomers Of Cyclopropane
- Conformations - Vector stencils library | Design elements ...
- Drawing Of Isomers Of Cyclopropane
- Cyclopentane Conformation
- Drawn The Isomer Cyclopropane And Comformation
- Half Chair Conformation Of Cyclopentane
- How to Draw Chemistry Structures | Chemistry | Conformations ...
- Cycloalkanes conformations | Half Chair Cyclopentane