Process Flow Diagram

This process flow diagram (PFD) example shows an amine treating system for the removal of gaseous hydrogen sulfide from gas streams. It is used in oil refineries and chemical plants. This PFD sample was redesigned from the Wikimedia Commons file: AmineTreating.png. [commons.wikimedia.org/ wiki/ File:AmineTreating.png]
This file is licensed under the Creative Commons Attribution-Share Alike 3.0 Unported license. [creativecommons.org/ licenses/ by-sa/ 3.0/ deed.en]
"Amine gas treating, also known as gas sweetening and acid gas removal, refers to a group of processes that use aqueous solutions of various alkylamines (commonly referred to simply as amines) to remove hydrogen sulfide (H2S) and carbon dioxide (CO2) from gases. It is a common unit process used in refineries, and is also used in petrochemical plants, natural gas processing plants and other industries.
Processes within oil refineries or chemical processing plants that remove hydrogen sulfide are referred to as "sweetening" processes because the odor of the processed products is improved by the absence of hydrogen sulfide. An alternative to the use of amines involves membrane technology. Membranes are attractive since no reagents are consumed.
Many different amines are used in gas treating:
Diethanolamine (DEA),
Monoethanolamine (MEA),
Methyldiethanolamine (MDEA),
Diisopropanolamine (DIPA),
Aminoethoxyethanol (Diglycolamine) (DGA).
The most commonly used amines in industrial plants are the alkanolamines DEA, MEA, and MDEA. These amines are also used in many oil refineries to remove sour gases from liquid hydrocarbons such as liquified petroleum gas (LPG)." [Amine gas treating. Wikipedia]
The PFD example "Amine treating unit schematic diagram" was drawn using the ConceptDraw PRO diagramming and vector drawing software extended with the Chemical and Process Engineering solution from the Chemical and Process Engineering area of ConceptDraw Solution Park.

This PFD of jet fuel mercaptan oxidation treating was redrawn from Wikipedia file: ConvLPGMerox.png. [en.wikipedia.org/ wiki/ File:ConvKeroMerox.png]
This file is licensed under the Creative Commons Attribution-Share Alike 3.0 Unported icense. [creativecommons.org/ licenses/ by-sa/ 3.0/ deed.en]
"Merox is an acronym for mercaptan oxidation. It is a proprietary catalytic chemical process developed by UOP used in oil refineries and natural gas processing plants to remove mercaptans from LPG, propane, butanes, light naphthas, kerosene and jet fuel by converting them to liquid hydrocarbon disulfides.
The Merox process requires an alkaline environment which, in some of the process versions, is provided by an aqueous solution of sodium hydroxide (NaOH), a strong base, commonly referred to as caustic. In other versions of the process, the alkalinity is provided by ammonia, which is a weak base.
The catalyst in some versions of the process is a water-soluble liquid. In other versions, the catalyst is impregnated onto charcoal granules.
Processes within oil refineries or natural gas processing plants that remove mercaptans and/ or hydrogen sulfide (H2S) are commonly referred to as sweetening processes because they results in products which no longer have the sour, foul odors of mercaptans and hydrogen sulfide. The liquid hydrocarbon disulfides may remain in the sweetened products, they may be used as part of the refinery or natural gas processing plant fuel, or they may be processed further.
The Merox process is usually more economical than using a catalytic hydrodesulfurization process for much the same purpose." [en.wikipedia.org/ wiki/ Merox]
The process flow diagram (PFD) example "Jet fuel mercaptan oxidation treating" was drawn using the ConceptDraw PRO software extended with the Chemical and Process Engineering solution from the Chemical and Process Engineering area of ConceptDraw Solution Park.