Carbonyl compound halogenation mechanism

This chemical reaction mechanism drawing depicts steps of carbonyl compound halogenation reaction.
"Alpha-substitution reactions occur at the position next to the carbonyl group, the α-position, and involve the substitution of an α hydrogen atom by an electrophile, E, through either an enol or enolate ion intermediate. ...
Alpha Halogenation of Aldehydes and Ketones.
A particularly common α-substitution reaction in the laboratory is the halogenation of aldehydes and ketones at their α positions by reaction Cl2, Br2 or I2 in acidic solution. Bromine in acetic acid solvent is often used. ...
The halogenation is a typical α-substitution reaction that proceeds by acid catalyzed formation of an enol intermediate." [Carbonyl Alpha-Substitution Reactions. Wikipedia]
This example was redesigned from the Wikimedia Commons file: Halogenierung Mechanismus Version 3-Seite001.svg. [commons.wikimedia.org/ wiki/ File:Halogenierung_ Mechanismus_ Version_ 3-Seite001.svg]
This image is available under the Creative Commons Attribution-ShareAlike 3.0 Unported License. [creativecommons.org/ licenses/ by-sa/ 3.0/ ]
The chemical drawing example "Carbonyl compound halogenation mechanism" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.

This sentence diagram sample was createb on the base of the webpage "Diagramming Sentences" from the website of the Capital Community College, Hartford CT. [grammar.ccc.commnet.edu/ grammar/ diagrams2/ one_ pager2.htm]
"In grammar, clause structure refers to the classification of sentences based on the number and kind of clauses in their syntactic structure. Such division is an element of traditional grammar.
A simple sentence consists of only one clause. A compound sentence consists of two or more independent clauses. A complex sentence has at least one independent clause plus at least one dependent clause.
A sentence consisting of one or more dependent clauses plus two or more independent clauses may be called a complex-compound sentence or compound-complex sentence. ...
A compound sentence is composed of at least two independent clauses. It does not require a dependent clause. The clauses are joined by a coordinating conjunction (with or without a comma), a semicolon that functions as a conjunction, a colon instead of a semicolon between two sentences when the second sentence explains or illustrates the first sentence and no coordinating conjunction is being used to connect the sentences, or a conjunctive adverb preceded by a semicolon. A conjunction can be used to make a compound sentence. Conjunctions are words such as for, and, nor, but, or, yet, so (the first letters of which spell "fanboys"). The use of a comma to separate two independent clauses without the addition of an appropriate conjunction is called a comma splice and is generally considered an error (when used in the English language)." [Sentence clause structure. Wikipedia]
The example "Compound sentence" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Language Learning solution from the Science and Education area of ConceptDraw Solution Park.

"There are two competing notions of the predicate in theories of grammar. The first concerns traditional grammar, which tends to view a predicate as one of two main parts of a sentence, the other part being the subject; the purpose of the predicate is to modify the subject. The second derives from work in predicate calculus (predicate logic, first order logic) and is prominent in modern theories of syntax and grammar. In this approach, the predicate of a sentence corresponds mainly to the main verb and any auxiliaries that accompany the main verb, whereas the arguments of that predicate (e.g. the subject and object noun phrases) are outside the predicate." [Predicate (grammar). Wikipedia]
The sentence diagram example "Compound predicate with one direct object" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Language Learning solution from the Science and Education area of ConceptDraw Solution Park.

This sentence diagram sample was createb on the base of the webpage "Diagramming Sentences" from the website of the Capital Community College, Hartford CT. [grammar.ccc.commnet.edu/ grammar/ diagrams2/ one_ pager2.htm]
"In grammar, clause structure refers to the classification of sentences based on the number and kind of clauses in their syntactic structure. Such division is an element of traditional grammar.
A simple sentence consists of only one clause. A compound sentence consists of two or more independent clauses. A complex sentence has at least one independent clause plus at least one dependent clause.
A sentence consisting of one or more dependent clauses plus two or more independent clauses may be called a complex-compound sentence or compound-complex sentence. ...
A compound sentence is composed of at least two independent clauses. It does not require a dependent clause. The clauses are joined by a coordinating conjunction (with or without a comma), a semicolon that functions as a conjunction, a colon instead of a semicolon between two sentences when the second sentence explains or illustrates the first sentence and no coordinating conjunction is being used to connect the sentences, or a conjunctive adverb preceded by a semicolon. A conjunction can be used to make a compound sentence. Conjunctions are words such as for, and, nor, but, or, yet, so (the first letters of which spell "fanboys"). The use of a comma to separate two independent clauses without the addition of an appropriate conjunction is called a comma splice and is generally considered an error (when used in the English language)." [Sentence clause structure. Wikipedia]
The example "Compound sentence" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Language Learning solution from the Science and Education area of ConceptDraw Solution Park.

This chemical drawing example shows structural formulas of organic molecules - polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons: naphthalene, anthracene, triphenylene, acenaphthylene, phenanthrene, pyrene.
"Polycyclic aromatic hydrocarbons (PAHs), also known as poly-aromatic hydrocarbons or polynuclear aromatic hydrocarbons, are fused aromatic rings and do not contain heteroatoms or carry substituents. Naphthalene is the simplest example of a PAH. PAHs occur in oil, coal, and tar deposits, and are produced as byproducts of fuel burning (whether fossil fuel or biomass).
They are potent atmospheric pollutants. Some compounds have been identified as carcinogenic, mutagenic, and teratogenic. PAHs are also found in cooked foods. Studies have shown that high levels of PAHs are found, for example, in meat cooked at high temperatures such as grilling or barbecuing, and in smoked fish.
They are also found in the interstellar medium, in comets, and in meteorites and are a candidate molecule to act as a basis for the earliest forms of life." [Polycyclic aromatic hydrocarbon. Wikipedia]
The chemical drawing example "PAH compounds" was created using the ConceptDraw PRO diagramming and vector drawing software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.

The vector stencils library "Aromatics" contains 23 symbols of aromatic rings for chemical drawing of molecular structural formulas and reaction mechanism schemes in organic chemistry.
"In organic chemistry, aromaticity is a chemical property describing the way in which a conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibits a stabilization stronger than would be expected by the stabilization of conjugation alone. ... Aromaticity can also be considered a manifestation of cyclic delocalization and of resonance. This is usually considered to be because electrons are free to cycle around circular arrangements of atoms that are alternately single- and double-bonded to one another. These bonds may be seen as a hybrid of a single bond and a double bond, each bond in the ring identical to every other. This commonly seen model of aromatic rings, namely the idea that benzene was formed from a six-membered carbon ring with alternating single and double bonds (cyclohexatriene), was developed by Kekulé (see History section below). The model for benzene consists of two resonance forms, which corresponds to the double and single bonds superimposing to give rise to six one-and-a-half bonds. Benzene is a more stable molecule than would be expected without accounting for charge delocalization. ... Types of aromatic compounds. The overwhelming majority of aromatic compounds are compounds of carbon, but they need not be hydrocarbons. 1. Neutral homocyclics. Benzene, as well as most other annulenes (cyclodecapentaene excepted) with the formula CnHn where n is an even number, such as cyclotetradecaheptaene. 2. Heterocyclics. In heterocyclic aromatics (heteroaromats), one or more of the atoms in the aromatic ring is of an element other than carbon. This can lessen the ring's aromaticity, and thus (as in the case of furan) increase its reactivity. Other examples include pyridine, pyrazine, imidazole, pyrazole, oxazole, thiophene, and their benzannulated analogs (benzimidazole, for example). 3. Polycyclics. Polycyclic aromatic hydrocarbons are molecules containing two or more simple aromatic rings fused together by sharing two neighboring carbon atoms (see also simple aromatic rings). Examples are naphthalene, anthracene, and phenanthrene. 4. Substituted aromatics. Many chemical compounds are aromatic rings with other functional groups attached. Examples include trinitrotoluene (TNT), acetylsalicylic acid (aspirin), paracetamol, and the nucleotides of DNA. 5. Atypical aromatic compounds. Aromaticity is found in ions as well: the cyclopropenyl cation (2e system), the cyclopentadienyl anion (6e system), the tropylium ion (6e), and the cyclooctatetraene dianion (10e). Aromatic properties have been attributed to non-benzenoid compounds such as tropone. Aromatic properties are tested to the limit in a class of compounds called cyclophanes. A special case of aromaticity is found in homoaromaticity where conjugation is interrupted by a single sp³ hybridized carbon atom. When carbon in benzene is replaced by other elements in borabenzene, silabenzene, germanabenzene, stannabenzene, phosphorine or pyrylium salts the aromaticity is still retained. Aromaticity also occurs in compounds that are not carbon-based at all. Inorganic 6-membered-ring compounds analogous to benzene have been synthesized. Hexasilabenzene (Si6H6) and borazine (B3N3H6) are structurally analogous to benzene, with the carbon atoms replaced by another element or elements. In borazine, the boron and nitrogen atoms alternate around the ring." [Aromaticity. Wikipedia]
The organic compound structural formulas example "Aromatics - Vector stencils library" was created using the ConceptDraw PRO software extended with the Chemistry solution from the Science and Education area of ConceptDraw Solution Park.

"IDEF0, a compound acronym (Icam DEFinition for Function Modeling, where 'ICAM' is an acronym for Integrated Computer Aided Manufacturing) is a function modeling methodology for describing manufacturing functions, which offers a functional modeling language for the analysis, development, reengineering, and integration of information systems; business processes; or software engineering analysis.
IDEF0 is part of the IDEF family of modeling languages in the field of software engineering, and is built on the functional modeling language Structured Analysis and Design Technique (SADT). ...
FIPS PUB 183 "Integration Definition for Function Modeling (IDEF0)," was withdrawn as a Federal Standard (in favor of OPEN Specifications and Standards) September 2, 2008, as cited in "The Federal Register", Volume 73, page 51276 (73FR/ 51276). ...
IDEF0, used to produce a "function model". A function model is a structured representation of the functions, activities or processes within the modeled system or subject area." [IDEF0. Wikipedia]
The template "IDEF0 diagram" is included in the IDEF0 Diagrams solution from the Software Development area of ConceptDraw Solution Park.